Product ID:609, LATEX AGRICULTURE COATING
MSDS Date:08/01/1990
FSC:8010
NIIN:00N031637
MSDS Number: BPJXT

O BRIEN CORP

450 EAST GRAND AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-338-8084 OR 415-761-2300

Preparer: CECILIA R.STODDARD

Cage: 30806

O BRIEN CORPORATION

SOUTH SAN FRANCISCO, CA 94080-6207 US

Cage: 72556

STUDIES SHOW THAT INHAL EXPOS TO HIGH LEVELS

RTECS: 9999999ZZ

LAB STUDIES SHOW VINYL ACETATE MAY BE

RTECS: 9999999ZZ

SKIN CNTCT CAN CAUSE ALLERGIES, SENSIT & DERM.

RTECS: 9999999ZZ

0.1.

CAS: 57-55-6

RTECS: TY2000000

Fraction By Weight: <5%

SILICON DIOXIDE, AMORPHOUS; (SILICA AMORPHOUS)

CAS: 7631-86-9

Fraction By Weight: 10%

PROPIONIC ACID, 2-METHYL-, MONOESTER

CAS: 25265-77-4

RTECS: UF6000000

Fraction By Weight: <5%

MONOISOBUTYRATE

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

ACETIC ACID, VINYL ESTER; (VINYL ACETATE) (SARA III)

CAS: 108-05-4

RTECS: AK0875000

Fraction By Weight: <0.1%

OSHA PEL 10 PPM/15 STEL

ACGIH TLV: 10 PPM/15,A3 STEL;93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANOL, 2-(2-BUTOXYETHOXY)-; (2-(2-BUTOXYETHOXY)ETHANOL).

CAS: 112-34-5

RTECS: KJ9100000

Fraction By Weight: <5%

IRRIT & POSS CHEM BURNS.

RTECS: 9999999ZZ

IRRIT TO UPPER

RTECS: 9999999ZZ

IRRIT TO UPPER

RTECS: 9999999ZZ

IRRIT MORE SEVERE UPON PRLNGD CNTCT.

RTECS: 9999999ZZ

CAN BE ABSORBED IN

RTECS: 9999999ZZ

BEEN SHOWN TO CAUSE SILICOSIS, PROGRESSIVE LUNG

RTECS: 9999999ZZ

STUDIES SHOW ETHYLENE GLYCOL CAUSES BIRTH DEFECTS &

RTECS: 9999999ZZ

BEEN ASSOC W/HIGHER INCIDENCES OF CANCERS IN HUMANS.

RTECS: 9999999ZZ

PRLNGD/RPTD CNTCT CAN CAUSE DERM/SENSIT. EVID

RTECS: 9999999ZZ

CALCIUM CARBONATE

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 5-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <5%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

SILICA, CRYSTALLINE - CRISTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: <5%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.05 MG/M3 RDUST9293

0.08. (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: <5%

OSHA PEL 50 PPM, C

ACGIH TLV: 50 PPM, MIST, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1095. (SARA III)

CAS: 75-21-8

RTECS: KX2450000

Fraction By Weight: <0.1%

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

19.5. (SARA III)

CAS: 50-00-0

RTECS: LP8925000

Fraction By Weight: <0.1%

OSHA PEL SEE 1910.1048

ACGIH TLV: C 0.3 PPM; A2; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:EYE:PRIMARY IRRIT. INHAL:MAY
CAUSE HDCH & NAUSEA. SKIN:POSS PRIMARY IRRIT. ING 1:INHAL:IRRIT TO
UPPER RESP TRACT. EYE:IRRIT. ING 4:INGEST:SINGLE LETHAL ORAL DOSE
FOR HUMANS IS ABOUT 3-4 OZ. WHEN INGESTED, MAY CAUSE INITIAL CNS
STIMULATION FOLLOWED BY DEPRESS. INHAL:EFTS INCLUDE RESP IRRIT &
LUNG (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: IARC (2A), NTP (2)
Effects of Overexposure:HLTH HAZ:INJ/HDCH/NAUSEA/VOMIT/DIARRHEA/ SHORT
OF BREATH & CYANOSIS. EYE:MAY CAUSE IRRIT & IRIDOCYCLITIS. SKIN:MAY
CAUSE IRRIT. ABSORP MAY CONTRIBUTE TO TOX SYMPS. ING 5:INGEST:MAY
CAUSE VOMIT & DIARR HEA. INHAL:DMG & SYMPS INCLUDE
HDCH/DIZZ/COUGH/DFCLT BRTHG/ NAUSEA/CNS DEPRESS & PULM
EDEMA(DELAYED). EYE:LIQ (SUPP DATA
Medical Cond Aggravated by Exposure:ING 2:MAY AGGRAVATE EXISTING LUNG
DISEASES; A LUNG TOXIN. ING 6:MAY AGGRAVATE EXISTING SKIN
CONDITIONS. ING 12:MAY AGGRAVATE EXISTING SKIN & RESPIRATORY
CONDITIONS.

First Aid:INGEST:DRINK 1-2 GLASSES OF WATER & INDUCE VOMIT BY PLACING
FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSON. CALL MD/POISONG CTL CTR IMMED. INHAL:REMOVE TO FRESH AIR.
RESTORE BR THG. EYE:IMMED BEGIN FLUSHING W/COOL WATER, OCCASNLY
LIFTING LIDS TO ENSURE THORO RINSING. CONTINUE FOR AT LEAST 15 MIN.
WHILE FLUSHING, CALL MD. SKIN:WASH THORO W/SOAP & WATER. REMOVE
CONTAMD CLTHG.

Flash Point:200F,93C
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.

Spill Release Procedures:SOAK UP & REMOVE W/INERT ABSORBENT MATERIAL.
PROVIDE ADEQUATE VENTILATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP FROM FREEZING. AVOID PROLONGED
CONTACT W/SKIN.
Other Precautions:DO NOT INGEST. KEEP OUT OF THE REACH OF CHILDREN.

Respiratory Protection:USE NIOSH/MSHA APPROVED MECHANICAL RESPIRATOR OR
MASK TO AVOID BREATHING VAPOR OR SPRAY MIST.
Ventilation:PROVIDE SUFFICIENT VENT IN VOLUME & PATTERN TO KEEP AIR
CONTAM CONC BELOW APPLICABLE OSHA PEL/ACGIH'S TLV LIMIT.
Protective Gloves:NONE REQUIRED. IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE COVERALLS RECOMMENDED.
Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHING. DISCARD
CONTAMINATED SHOES.
Supplemental Safety and Health
EFTS OF OVEREXP:MAY CAUSE BURNS. SKIN:LIQ CAN CAUSE BURNS. MAY CAUSE
ECZEMA-LIKE SENSIT. ING 6:INGEST:IRRIT & INFLAMM OF
MOUTH/THROAT/STOM. SEVERE ABDOM PAIN, POSS UNCON. INHAL:HIGHLY
IRRIT & INFLAMIN G TO UPPER RESP TRACT. POSS BRONCHIOPNEUMONIA.
EYE:SEVERE IRRIT(ING 14)

HCC:N1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:SEE INGRED
Vapor Density:LTR/AIR
Spec Gravity:1.32
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:65

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CO, CO2 & NO2.

Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT INCINERATE IN CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.